B.Sc. Third year (UG degree course) Semester Fifth, Physical chemistry paper-XIII
Chapter – Photochemistry
Multiple choice Questions 1. Which of the following statements about the photochemical reactions is true?
a) the presence of light is the primary requirement for reactions to take place
b) temperature has a very little effect on the rate of photochemical reactions
c) ΔG for photochemical spontaneous reactions may +ve or –ve
d) all of the above
2. “It is only the absorbed light radiations that are effective in producing a chemical reaction.” This is the statement of
a) Lambert law
b) Lambert-Beer law
c) Grothus-Draper law
3. “In a photochemical
reaction each molecule of the reacting substance absorbs a single photon of radiation
causing the reaction and is activated to form the products.” This is the
statement of
a) Lambert-Beer’s law
b) Grothus-Draper law
c) Stark-Einstein law
d) Lambert’s law
4. For a reaction that
obeys Einstein law,
a) φ = 1
b) φ > 1
c) φ < 1
d) φ = 0
5. In some
photochemical reactions low quantum yield is obtained. It is due to
a) deactivation of
reacting molecules
b) occurrence of reverse
primary reaction
c) recombination of
dissociated fragments
d) all of these
6. The energy
associated with a photon is given by the equation
a) ∈ = h × Î»
b) ∈ = h × v
c) ∈ = h × c
d) ∈ = h × c2
7. One einstein is the
energy associated with
a) one molecule
b) one photon
c) Avogadro number of
photons
d) Faraday number of
photons
8. A species which can
both absorb and transfer radiant energy for activation of the reactant molecule
is called
a) radioactive substance
b) an ioniser
c) a photochemical
substance
d) a photosensitizer
9. The reactions which
are caused by heat and in absence of light are called
a) photochemical
reactions
b) catalytic reactions
c) exothermic reactions
d) thermal or dark
reactions
10. “Only the fraction
of incident light that is absorbed by the substance can bring about a chemical change”.
is
a) First law of
photochemistry
b) Second law of
photochemistry
c) Third law of
photochemistry
d) none of these
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