Photochemistry MCQ- B.Sc. Third year (UG degree course) Semester Fifth, Physical chemistry paper-XIII (Part 2)

 B.Sc. Third year (UG degree course) Semester Fifth, Physical chemistry paper-XIII

Chapter – Photochemistry

Multiple choice Questions

1. Which of the following statements about the photochemical reactions is true?
a)  the presence of light is the primary requirement for reactions to take place
b) temperature has a very little effect on the rate of photochemical reactions
c)  ΔG for photochemical spontaneous reactions may +ve or –ve
d) all of the above
 
2. “It is only the absorbed light radiations that are effective in producing a chemical reaction.” This is the statement of
a)  Lambert law
b) Lambert-Beer law
c) Grothus-Draper law 
d)  Stark-Einstein law

 

3. “In a photochemical reaction each molecule of the reacting substance absorbs a single photon of radiation causing the reaction and is activated to form the products.” This is the statement of

a)  Lambert-Beer’s law

b) Grothus-Draper law

c) Stark-Einstein law

d) Lambert’s law

 

4. For a reaction that obeys Einstein law,

a) φ = 1

b) φ > 1

c)  φ < 1

d) φ = 0

 

5. In some photochemical reactions low quantum yield is obtained. It is due to

a)  deactivation of reacting molecules

b) occurrence of reverse primary reaction

c)  recombination of dissociated fragments

d) all of these

 

6. The energy associated with a photon is given by the equation

a)  = h × Î»

b) = h × v

c)  = h × c

d) = h × c2

 

7. One einstein is the energy associated with

a)  one molecule

b) one photon

c) Avogadro number of photons

d) Faraday number of photons

 

8. A species which can both absorb and transfer radiant energy for activation of the reactant molecule is called

a)  radioactive substance

b) an ioniser

c)  a photochemical substance

d) a photosensitizer

 

9. The reactions which are caused by heat and in absence of light are called

a)  photochemical reactions

b) catalytic reactions

c)  exothermic reactions

d) thermal or dark reactions

 

10. “Only the fraction of incident light that is absorbed by the substance can bring about a chemical change”. is

a) First law of photochemistry

b) Second law of photochemistry

c)  Third law of photochemistry

d) none of these


More questions 
Part1 Click here 
Part2 Click here 
Part 3 Click here
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