Water treatment and analysis (SEC-1) B.Sc. Undergraduate course as per New education policy (NEP) Part -III

 

Sources of Pollution - Physical, Chemical, Organic & Biological properties of Industrial Wastewater:

I. Physical characteristics of sewage:

1. Temperature:

Ø Temperature of sewage depends upon season. However temperature is slightly higher than that of ground water.

Ø High temperature of sewage is due to evolution of heat during decomposition of organic matter in sewage.

2. Color:

Ø Color of sewage indicates its strength and age.

Ø Fresh domestic sewage is grey in color but septic sewage is dark in color

Ø When industrial effluent is mixed it give characteristic color to sewage

3. Odor:

Ø Fresh domestic sewage is almost odorless.

Ø Septic or stale sewage is putrid in odor which is due to generation of H2S during anaerobic decomposition of organic matters.

Ø When industrial effluent is mixed, it give characteristics odor to sewage

4. Turbidity:

Ø Sewage is highly turbid.

Ø Turbidity of sewage is due to dissolved substances, colloidal matters, suspended solids and microbial cells.

II. Chemical characteristics of sewage:

1. Organic matter:

In general sewage contains large amount of organic matters. However amount of organic matter depends on types and condition of sewage.

Organic matter in sewage may be found in the form of dissolved substances, colloidal matter, suspended or sedimented form.

2. Chloride:

Human beings discharge large amount (8-15gm/day) of chloride in the form of NaCl, especially through urine and sweat. So domestic sewage from toilet and bathroom contains higher level of chloride.

Sulfite:

In sewage sulfite in the form of H2S (hydrogen sulfite) is generated during anaerobic decomposition of organic matters by anaerobic bacteria. H2S gives putrid odor to sewage.

3. Biological oxygen demand (BOD):

Sewage usually have high BOD due to presence of large amount of organic matters. Value of BOD ranges from 100mg/ltr for very dilute sewage to 600mg/ltr or more for concentrated sewage containing industrial effluent mix.

4. Dissolved oxygen (DO):

 

Due to high level of microbial cells and biodegradable organic matters, sewage have very low level of dissolved oxygen.

In some sewage, DO is completely absent. Level of DO depends on age and condition of sewage. Low level DO is also due to lower solubility of oxygen in sewage. Oxygen is only 95% soluble in sewage than in pure water).

5. pH:

Sewage is slightly alkaline in pH.

6. Nitrogen:

Ø In sewage nitrogen is found in variety of form like organic nitrogen, ammonia, nitrite, nitrate etc

Ø Fresh sewage mainly contains organic nitrogen and very little inorganic form of nitrogen. On the other hand organic septic sewage contains high inorganic nitrogen and low organic nitrogen.

Ø In sewage nitrite never accumulate in concentration greater than 1mg/ltr because it is intermediate product during conversion of ammonia into nitrate (NO3).

Ø In sewage treatment plant, NH3 and NO2 are finally converted to NO3.

III. Biological characteristics of sewage:

1. Bacteria:

Two types of bacteria are found in sewage.

Intestinal bacteria:

Non-pathogenic intestinal bacteria are normal flora of gasto intestinal tract of human and animals and enter into sewage together with stool. Examples; faecal coliform, faecal streptococci, Clostridium perfingens, etc.

Pathogenic intestinal bacteria such as Salmonella, Shigella, Vibrio cholera, Yersenia enterocolitica etc enter into sewage through stool of patients.

Real sewage bacteria

The natural habitat of these bacteria is sewage.Both aerobic as well as anaerobic are found in sewage. Aerobic bacteria play important role in oxidation of organic matter during aerobic process.

Common anaerobic bacteria includes;

Clostridium sporogens

Bifidobacterium

Peptococcus

Methanogenic bacteria like Methanobacterium, methanosarcina

Common aerobic bacteria includes;

Zeoglea remigera

Noacrdia

Flavobacterium

Achromobacter

Nitrosomonas

2. Algae:

Some algae found in sewage includes Chlorella phormidum, Ulothrix etc Algae are used in trickling filter in sewage treatment plant

3. Fungi:

Fungi like Fusarium and Sporotricum are found in sewage which play important role in trickling filter.

4. Virus:

Some viruses causing human disease such as Poliovirus, Rotavirus, Hepatitis A and E etc are found in sewage which get access through stool of patients.

5. Protozoa:

Some protozoa that cause disease of intestinal tract enter into sewage together with stool of patient.

Examples: Entamoeba histolytica, Giardia, Balantidium coli etc are pathogenic protozoa Few protozoa such as Vorticella and Opercularia are found in trickling filter.

Difference between industrial; municipal waste waters:

Industrial waste water

Municipal Waste water

Industrial wastewater consists of wastes originating from the industrial processes of various industries such as paper manufacture, textile, sugar, brewing, dyeing etc.

 

Municipal waste water consists of liquid waste originating from bathrooms, water closets, kitchen sinks, wash basins etc of residential, commercial or institutions buildings.

For examples apartments, hotels, hospitals, shopping mall etc

The quality of industrial wastewater depends largely upon the type of industry & the chemicals used in their process water

Municipal water contains same type of pollutants.

Contains several chemical pollutants & toxic substances in too large proportions.

Do not contain very toxic chemicals.

 

 

Effects of industrial effluents on Natural water Bodies.

  Chemical Contamination: Industrial effluents may contain toxic chemicals such as ammonia, nitrates, phosphates, and other hazardous substances like pesticides and hydrocarbons. These can lead to the poisoning of aquatic ecosystems, harming fish, plants, and other organisms.

  Heavy Metals: Metals like mercury, lead, and cadmium are commonly found in industrial waste. These accumulate in water bodies and in the tissues of aquatic organisms, leading to bioaccumulation and biomagnification, affecting the entire food chain.

  pH Alterations: Effluents can alter the pH of water bodies, making them either too acidic or too alkaline for the survival of aquatic species. Extreme pH changes can kill fish and other marine life, destroy coral reefs, and reduce biodiversity.

Eutrophication

Industrial effluents containing high levels of nutrients like nitrogen and phosphorus can lead to eutrophication, which causes excessive algae growth in water bodies. When algae die and decompose, it depletes oxygen levels in the water, creating hypoxic conditions or dead zones where most aquatic life cannot survive.

Thermal Pollution

Some industries release heated water into natural water bodies. This thermal pollution can disrupt the local ecosystem by altering the temperature of the water, affecting species that are sensitive to temperature changes. Warmer waters hold less dissolved oxygen, further stressing aquatic organisms and reducing biodiversity.

Impact on Human Health

Contaminated water sources may enter human food chains through fish and seafood consumption, posing serious health risks, including cancer, neurological damage, and other chronic illnesses.

Industrial effluents that pollute drinking water sources can lead to diseases such as gastrointestinal issues, liver and kidney damage, and other waterborne diseases.

Effect of sewage on Natural water bodies:

Methane and Greenhouse Gas Emissions

The decomposition of organic matter from sewage under anaerobic (oxygen-limited) conditions produces methane, a potent greenhouse gas. Methane emissions from sewage-contaminated water bodies contribute to climate change and exacerbate environmental problems.

Impact on Drinking Water Sources

Sewage contamination of rivers, lakes, and groundwater can affect drinking water supplies. Even small amounts of untreated sewage can make water unsafe for human consumption, leading to serious public health risks. This is especially dangerous for communities that rely on untreated or minimally treated water sources.

Toxicity from Heavy Metals and Chemicals

Some sewage contains heavy metals like mercury, lead, and cadmium from household waste, industries, and stormwater runoff. These metals can accumulate in the tissues of aquatic organisms, leading to bioaccumulation and biomagnification throughout the food chain, affecting fish, birds, and even humans.

Pharmaceuticals and personal care products from sewage can interfere with the hormonal and reproductive systems of aquatic organisms.

Pathogen Contamination

Untreated or partially treated sewage contains pathogens such as bacteria, viruses, and parasites (e.g., E. coli, cholera, giardia, and cryptosporidium). These pathogens can contaminate water bodies, posing risks to both aquatic life and human health.

Water contaminated with pathogens can spread waterborne diseases such as cholera, dysentery, and hepatitis among people who use the water for drinking, bathing, or recreational purposes.

Water treatment and analysis Part-I

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Water treatment and analysis Part-II

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Water treatment and analysis Part-III

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