Analytical chemistry unit-2 MCQ M.Sc. Chemistry First year first semester

  M. Sc. First year Postgraduate degree course

First Semester

CHE - 101

ANALYTICAL CHEMISTRY

Statistical Treatment of analytical data:

Introduction, types of errors, significant figures, precision and accuracy, methods of expressing accuracy, methods of expressing precision, the confidence limit, fests of significance the test, the student T test, rejection of results - the Q  test. Statistics for small data sets, linear least squares, correlation coefficient, using spreadsheets for plotting calibration curves, slope, intercept and coefficient of determination, numerical. 

Multiple Choice questions:

1. Which of the following is an error that may occur in the measurement of a physical quantity …
a)  Systematic error
b) Random error
c)  Absolute error
d) All of the above

2. Which of the following is type of systematic error….
a)  Instrumental error
b) Gross error
c)  Error due to imperfections
d) All of the above

3. In an experiment, it is found that the experimental value is very close to actual value, hence the experimental value can be called _____
a) Accurate
b) Precise
c) Suitable
d) Mean

4.  What is the reason for the occurrence of systematic errors in an instrument?
a) No use for a long time
b) High use
c) Manufacturing fault
d) Delivery fault

5. How are systematic errors removed usually for an instrument?
a) By replacing it
b) By re-calibrating it
c) By using a repairing service
d) By not using it for some time

6. in 5 experiments with the same objective, the values obtained are very near to each other. These values can be called ____
a) precise
b) Accurate
c) Average
d) Invalid

7.Mesurement that is close to the true value called as
a)  Accurate
b) Average
c)  Precise
d) Error
8888

8.Which of the following is type of determinate error..
a)  Instrumental error
b) Operative error
c)  Error of method
d) All of the above

9.In the set 10.2,10.4,10.8,11.0,11.2 the median is….
a)  10.4
b) 10.8
c)  11.0
d) 11.2

10. The F test is used ……
a)  For rejection of data
b) For testing of significance
c)  For obtaining best fitting line
d) For completion of data

11.Method of averages is used…….
a)  For rejection of data
b) For testing of significance
c) For obtaining best fitting line
d) For completion of data

12.For rejection of result, the test used is…..
a)  F-test
b) Testing of significance
c) Q-Test
d) T-test

13. Standard deviation for the following set of results 10.28,10.24,10.25,10.25.10.30
a) 0.0187
b) 10.26
c)  10.25
d) 0.223

14.For rejection of result which of the following rule is used…..
a)  2.5d rule
b) 4.0d rule
c) Both a and b 
 d) None of these

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